Hello,
if you have installed the 32-bit runtime environment libraries on the 64-bit operating system, then it should work.
The SAP GUI itself is only available for 32-bit operating systems. This means you should use the 32-bit libraries in conjunction with the SAP GUI. When using it without the SAP GUI you are free to also use the 64-bit versions if you have a 64-bit operating system on your side.
SAP currently delivers software via the service marketplace (SMP). If you have the material number you may have the chance to also order it on CD/DVD in the SAP shop (if this was your question).
Please reward points if helpful.
Regards,
Juergen